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Frontier News

Strategies for improving the oxidation and corrosion resistance of graphene absorbing materials

Time:2024-12-25Number:270

1、 Introduction


With the rapid development of electronic devices and the increasingly complex electromagnetic environment, graphene absorbing materials have received widespread attention for their excellent absorbing properties. However, in practical applications, its lack of oxidation and corrosion resistance limits its long-term stability and reliability. Developed by Advanced Institute (Shenzhen) Technology Co., Ltd Research Platinum Graphene Absorbing MaterialsThere are also challenges and opportunities in this regard. Improving its antioxidant and anti-corrosion properties is of crucial importance for expanding the application areas and extending the service life of this material.

2、 Oxidation and Corrosion Mechanisms of Graphene Absorbing Materials


(1) Oxidation mechanism
Graphene has high chemical activity, especially its edges and defect sites are prone to react with oxygen in the air. In harsh environments such as high temperature and high humidity, the oxidation process accelerates, leading to the destruction of the structure of graphene and affecting its absorption performance. After oxygen molecules are adsorbed on the surface of graphene, they will form oxygen-containing functional groups through a series of chemical reactions, such as hydroxyl and carboxyl groups. These functional groups will change the electronic structure and electrical properties of graphene, reducing its conductivity and stability.

(2) Corrosion mechanism
When graphene absorbing materials are exposed to corrosive media such as acidic, alkaline solutions, or salt spray environments, corrosion occurs. Corrosive ions can penetrate into the lattice of graphene, react chemically with carbon atoms, and cause damage to the crystal structure of graphene. Meanwhile, the corrosion process may also trigger localized electrochemical corrosion, further accelerating material degradation. A deep understanding of the oxidation and corrosion mechanisms of platinum brand graphene absorbing materials is the basis for developing effective protective measures. 吸波材料

3、 Technical means to enhance antioxidant performance


(1) Surface modification and coating

  1. Organic molecule modification: Organic molecules with antioxidant properties, such as polyphenolic compounds and amine compounds, are introduced onto the surface of graphene through chemical grafting. These organic molecules can react with oxygen free radicals to prevent further erosion of graphene by oxygen. For example, molecules containing multiple phenolic hydroxyl groups are covalently bound to active sites on the surface of graphene to form an antioxidant protective film, effectively delaying the oxidation process.
  2. Inorganic coating: Using physical vapor deposition (PVD) or chemical vapor deposition (CVD) techniques, a thin and dense inorganic coating is deposited on the surface of graphene, such as aluminum oxide (Al ₂ O3), silicon dioxide (SiO ₂), etc. These inorganic coatings have good antioxidant properties and can block direct contact between oxygen and graphene.Advanced Institute (Shenzhen) Technology Co., LtdIt can optimize the deposition process parameters to ensure the uniformity and integrity of the coating, and improve the oxidation resistance of the research platinum brand graphene absorbing material.

(2) Doping modification
Introducing other atoms such as nitrogen (N) and boron (B) into the graphene lattice for doping can alter the electronic structure of graphene and improve its antioxidant properties. Nitrogen doping can increase the electron cloud density on the surface of graphene, enhance its adsorption capacity for oxygen radicals, and thus suppress the occurrence of oxidation reactions. By controlling the doping concentration and process conditions, the oxidation resistance of graphene can be precisely adjusted to maintain good stability in different environments.

(3) Composite antioxidant
Composite various materials with antioxidant properties with graphene to form a synergistic antioxidant system. For example, combining graphene with transition metal oxides (such as MnO ₂, TiO ₂, etc.) and antioxidants. Transition metal oxides can serve as catalysts to promote the regeneration of antioxidants, allowing them to continuously exert their antioxidant effects and effectively enhance Graphene absorbing materialThe overall antioxidant performance. 吸波材料

4、 Methods to enhance corrosion resistance


(1) Passivation treatment
Passivation treatment is applied to graphene absorbing materials to form a stable passivation film on their surface. For example, using chemical passivators (such as chromate, phosphate, etc.) to treat materials, a dense passivation film is formed on the surface to block the invasion of corrosive ions. However, considering environmental requirements, Advanced Institute (Shenzhen) Technology Co., Ltd. can explore the development of chromium free passivation processes, such as using environmentally friendly passivators such as molybdate and tungstate, to ensure corrosion resistance while reducing environmental pollution and improving Research Platinum Graphene Absorbing MaterialsThe green and environmentally friendly characteristics.

(2) Alloying and Composite Material Construction

  1. Alloying: Composite graphene with metals or alloys with good corrosion resistance, such as stainless steel, nickel based alloys, etc. By using physical mixing or chemical synthesis methods, graphene is uniformly dispersed in the alloy matrix, and the corrosion resistance of the alloy is utilized to protect graphene. Meanwhile, the presence of graphene can also improve the mechanical and absorbing properties of the alloy, achieving a synergistic effect.
  2. Building multi-layer composite materials: designing and preparing composite materials with multi-layer structures, such as alternately stacking graphene with corrosion-resistant polymers (such as polytetrafluoroethylene, epoxy resin, etc.). The outer polymer layer can act as a physical barrier to prevent corrosive media from directly contacting graphene, while the inner graphene provides absorption function. This multi-layer structure can effectively improve the overall corrosion resistance of materials and meet the application requirements in complex environments.

(3) Electrochemical protection
Using electrochemical principles to provide cathodic or anodic protection for graphene absorbing materials. For example, by connecting a sacrificial anode (such as active metals like zinc and magnesium) to the surface of a material, when corrosion occurs, the sacrificial anode will be preferentially corroded, thereby protecting the graphene absorbing material from corrosion. Alternatively, by applying an external current, the material surface can be placed in a cathodic polarization state to suppress the occurrence of corrosion reactions. This electrochemical protection method can significantly improve the corrosion resistance life of Yanbo brand graphene absorbing materials in specific application scenarios, such as marine environments or chemical equipment. 吸波材料

5、 Performance testing and validation


(1) Antioxidant performance test
By using testing methods such as thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS), the properties of the samples before and after modification were analyzed Research Platinum Graphene Absorbing MaterialsStudy the oxidation behavior at different temperatures and atmospheres. Evaluate the effectiveness of antioxidant measures by measuring parameters such as mass loss, surface element composition, and chemical valence state changes during the oxidation process of materials. At the same time, combined with accelerated aging experiments, the material was exposed to a high temperature, high humidity, and high oxygen content environment for a certain period of time, and its absorption performance was tested to determine the effect of antioxidant treatment on the long-term stability of the material.

(2) Corrosion resistance test
Use testing methods such as salt spray test and electrochemical impedance spectroscopy (EIS) to evaluate the corrosion resistance of materials in corrosive media. Salt spray test can visually observe the corrosion situation on the surface of materials, such as the appearance of corrosion spots, coating peeling, etc. EIS can measure the electrochemical parameters of materials during the corrosion process, such as charge transfer resistance, double-layer capacitance, etc., in order to quantitatively evaluate the changes in the corrosion resistance of materials. By analyzing the test results and continuously optimizing the technical solutions to improve the corrosion resistance performance, we ensure the reliability of the research platinum brand graphene absorbing material in practical applications.

6、 Conclusion


The oxidation resistance of platinum brand graphene absorbing materials developed by Advanced Institute (Shenzhen) Technology Co., Ltd. can be effectively improved through surface modification and coating, doping modification, composite antioxidants, and other methods. Passivation treatment, alloying, composite material construction, and electrochemical protection can significantly enhance their corrosion resistance. In the actual research and production process, it is necessary to comprehensively consider factors such as the application environment, cost-effectiveness, and process feasibility of materials, and select appropriate technical means to optimize graphene absorbing materials. At the same time, continuous performance testing and verification are key links to ensure the improvement of material performance. Through continuous improvement and innovation, the research platinum brand graphene absorbing materials can achieve higher levels of oxidation and corrosion resistance, laying a solid foundation for their widespread application in electromagnetic protection, communication and other fields, and promoting technological progress and development in related industries.
The above data is for reference only, and specific performance may vary due to production processes and product specifications.
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