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Mass production plan for 3.1 μ m PET copper plated film and ultra-thin composite current collector
In the selection of ultra-thin PET copper plated film, engineers are faced with a seemingly simple choice: since the goal is "thinner and lighter", why not directly choose a substrate of 2.3 μ m or even thinner?
The answer lies at the intersection of process yield and engineering reliability. The 2.3 μ m PET substrate is approaching the physical limit of an independent film - during vacuum magnetron sputtering, the heat capacity of the film is extremely small, and even small temperature fluctuations can cause shrinkage or even melting; The winding tension window is extremely narrow, and slight tension deviation can cause wrinkles or tensile deformation. Industry data shows that the thickness of ultra-thin PET substrates that can be used for stable copper plating is usually above 3 μ m. Although 2.3 μ m is feasible in the laboratory, it still faces significant challenges in terms of mass production yield and batch consistency.
Core proposition:3.1 μ m is in a "just right" position in engineering: it is significantly thinner than 4 μ m or 6 μ m, bringing considerable weight reduction and space benefits to lithium battery composite current collectors and high-density FPCs; At the same time, it retains sufficient mechanical strength and thermal capacity margin, enabling coil to coil magnetron sputtering copper plating to operate stably within an acceptable yield range.Advanced Institute of TechnologyThe use of low-temperature and low stress deposition technology effectively reduces thermal damage to ultra-thin substrates during the magnetron sputtering bottom stage, avoiding film warping and brittleness, which is precisely the engineering optimization for the critical thickness range of 3.1 μ m.
The copper layer preparation of 3.1 μ m PET copper plated film adopts roll to roll vacuum magnetron sputtering process. In a highly vacuum environment, copper with a purity of 99.999% is used as the target material. High energy ions bombard the copper target material to sputter copper atoms, which are uniformly deposited on the surface of PET film under the action of electric and magnetic fields, forming a copper layer with uniform thickness and strong adhesion. On this basis, Advanced Institute Technology adopts a dry wet combination process of "magnetron sputtering as the base and pulse electroplating for thickening": the magnetron sputtering layer provides a high adhesion and low defect seed layer, while the pulse electroplating layer provides low resistivity and high density.
Copper plating on ultra-thin substrates with a thickness of 3.1 μ m faces a series of technical challenges that are far more stringent than conventional thickness substrates:
The thermal capacity of 3.1 μ m PET film is much smaller than that of 6 μ m or 12 μ m substrates. If too much heat accumulates during the sputtering process, the film will shrink, warp, or even puncture. Advanced Institute Technology controls the temperature rise of the substrate within a safe range through low-temperature magnetron sputtering as a substrate.
The mechanical strength of 3.1 μ m film is limited, and the tension window for unwinding and unwinding is extremely narrow. The roll to roll production line of Advanced Institute Technology is equipped with a high-precision tension control system to ensure smooth operation of the film in the sputtering chamber without stretching deformation.
The uniformity of copper layer thickness directly affects the conductivity and consistency of signal transmission. Advanced Institute Technology has achieved a square resistance uniformity of within ± 5% through an online square resistance scanning system, which is better than the industry average of 15%.
The lack of active functional groups on the surface of PET and insufficient adhesion between the metal coating and the substrate can lead to the detachment of the copper layer during subsequent processing. The plasma pretreatment process of Advanced Institute Technology effectively improves the bonding strength between PET and copper layer, with coating adhesion reaching 5B level (the highest level of ASTM D3359) and peel strength ≥ 8N/cm.
Based on 3.1 μ m PET substrate, copper plated film products with different copper layer thicknesses can be prepared by precise control of sputtering and electroplating process parameters. The thickness of the copper layer varies from 0.1 μ m to 1 μ m, and different thicknesses correspond to different performance focuses:
| Product Type | Copper Layer Thickness | Key Characteristics | Typical Applications |
|---|---|---|---|
| 3.1 0.1PET copper plated film | ~0.1 μm | Extremely thin copper layer, highest flexibility, semi transparent | High density FPC thin lines, sensor electrodes, precision optics |
| 3.1 0.3PET copper plated film | ~0.3 μm | Thin copper layer, good flexibility, moderate conductivity | Thin line distance FPC signal line, wearable device connection |
| 3.1 0.7PET copper plated film | ~0.7 μm | Medium copper layer, with balanced conductivity and flexibility | FPC signal line, electromagnetic shielding layer, flexible connection |
| 3.1 1PET copper plated film | ~1 μm | Thick copper layer, low square resistance, high conductivity | Lithium battery composite current collector, high-frequency signal transmission, electromagnetic shielding |
When selecting, engineers should weigh the requirements of conductivity, bending life, and processing accuracy comprehensively: the thinner the copper layer (0.1-0.3 μ m), the better the flexibility, and the higher the etching accuracy, which is suitable for high-precision thin circuits and transparent applications; The thicker the copper layer (0.7-1 μ m), the lower the square resistance, and the stronger the current carrying capacity and shielding effectiveness. Advanced Institute Technology's copper layer thickness covers 0.1-8 μ m, supporting flexible customization from ultra-thin to thickened. The typical value of square resistance for 1 μ m copper thickness is ≤ 18m Ω/□, and for 4 μ m copper thickness, the square resistance is ≤ 4.5m Ω/□.
ComprehensiveAdvanced Institute of TechnologyAccording to official website information, the key performance characteristics of 3.1 μ m PET copper plated film are as follows:
This is the most promising application direction for 3.1 μ m PET copper plated film. The composite copper foil adopts a sandwich structure of "PET base film double-sided copper plating", with 3.1 μ m PET as the middle support layer, and copper layers deposited on both sides. BYD patent data shows that using a composite copper foil with 1 μ m copper on top and bottom of a 3 μ m PP substrate instead of a 6 μ m traditional copper foil can increase battery weight and energy density by 3.3%; The weight reduction effect of composite copper foil can reach over 55% compared to traditional copper foil. The density of PET substrate is only about 1/6.5 of copper. By replacing some copper materials with PET, the surface density of the current collector is significantly reduced, which is directly converted into an increase in battery energy density. The polymer material layer produces a circuit breaking effect during thermal runaway, with small burr sizes, fundamentally reducing the risk of fire caused by internal short circuits in the battery. 3.1 1PET is the most representative specification for copper layer thickness in composite copper foil applications - a 1 μ m copper layer ensures conductivity while controlling the total thickness of the current collector within a compact range.
The ultra-thin PET substrate with a thickness of 3.1 μ m is suitable for FPC products that require high thinning and circuit accuracy. The thin copper layer (0.1-0.3 μ m) can achieve fine wiring after etching, suitable for high-density interconnect (HDI) FPC and sensor electrode applications. Advanced Institute Technology supports flexible adjustment of copper layer thickness, PET substrate functionalization, and patterned deposition, with a maximum width of 1350mm.
3.1 μ m PET copper plated film can be used as an ultra-thin electromagnetic shielding layer, which can be attached to narrow spaces that traditional shielding materials cannot enter. The high-purity oxygen free copper conductive layer deposited by magnetron sputtering endows the surface of PET film with metallic conductivity and thermal conductivity, making it suitable for heat dissipation, electrode circuits, and electromagnetic shielding applications in electronic products.
When engineers choose 3.1 μ m PET copper plated film, the following dimensions deserve special attention:
Selection warning:3.1 μ m is not a 'second best' choice - it is the optimal balance between mass production feasibility and weight reduction benefits. Although 2.3 μ m has laboratory feasibility, it still faces significant challenges in terms of copper plating yield and batch consistency; 4 μ m or 6 μ m sacrifices considerable weight reduction space. Understanding the boundaries of this project is more valuable than simply pursuing the 'thinnest'.
The essence of 3.1 μ m PET copper plated film is to find an engineering balance point between the physical limits of PET film and the feasibility of mass production. It is thinner than 4 μ m or 6 μ m, bringing tangible weight reduction and space benefits to lithium battery composite current collectors and high-density FPCs; At the same time, it retains sufficient process margin to ensure stable operation of coil to coil magnetron sputtering copper plating within an acceptable yield range.
From the measured results of BYD's patent data showing a 3.3% increase in energy density of 3 μ m composite copper foil, to the engineering implementation of advanced institute technology's low-temperature and low stress deposition process on ultra-thin substrates - behind the thickness figure of 3.1 μ m is a complete process system from substrate tension control, temperature management to coating uniformity and adhesion guarantee. For engineers, understanding why it is 3.1 μ m instead of 2.3 μ m or 4 μ m - the answer to this question is precisely the technological watershed for ultra-thin PET copper plated films to move from "capable plating" to "precision plating".
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